Episode 159
Ash finally arrives at the location of the Battle Pike ready to battle. Team Rocket tricks him into coming into their own fake Battle Pike where they capture Pikachu. With the help of the real Frontier Brain - Pike Queen Lucy, they save Pikachu. Ash challenges Lucy to a battle, and even though it is her day off, she accepts as she has a crush on Brock. Ash the two begin their battle Ash realizes Lucy is no pushover. Can Ash win? And who will Brock cheer for!
Aired 05/01/2006EP 159 - Episode 159

Pokémon the Series: Ruby and Sapphire
After participating in the Johto League, Ash decides to begin anew in yet another journey; this time by himself and Pikachu, in the land of Hoenn. Though he isn't alone for long, as 10-year-old May (who dislikes Pokemon, but just wants to come along to see the world) travels with him after Pikachu destroys her bicycle. Ash also meets up with his old companion, Brock, and May's younger brother, Max. Together, they travel along in Hoenn, battling Gym Leaders, entering Contests, and other events on the way to the Hoenn League.
(Source: Anime News Network)