Piplup, Up and Away!
Piplup is getting sick and tired of being constantly hit by Gible's failed Draco Meteor attacks. Fed up, Piplup runs away, and heads towards Professor Rowan's lab. Will Dawn be able to find her beloved Pokémon?
Aired 18/02/2010EP 164 - Piplup, Up and Away!

2006
Pokémon the Series: Diamond and Pearl
After defeating Brandon and declining the offer to be a Frontier Brain, Ash sets off to travel through the far away land of Sinnoh. Once he gets there, he meets up with Hikari, a local trainer from the region, and they decide to travel together.