Episode 190
With the Sinnoh League behind them, Ash and friends take a ship back to Dawn's hometown of Twinleaf. A crisis emerges, however, when a group of Tentacruel attack the ship and poison many of the Pokémon on board. With no other doctor on the ship, Brock is the only one who can help those Pokémon. Will he succeed before it's too late?
Aired 02/09/2010EP 190 - Episode 190

2006
Pokémon the Series: Diamond and Pearl
After defeating Brandon and declining the offer to be a Frontier Brain, Ash sets off to travel through the far away land of Sinnoh. Once he gets there, he meets up with Hikari, a local trainer from the region, and they decide to travel together.