Episode 36
The day before the Kalos League finals between Ash and Alain, our heroes meet Alain’s young friend Mairin when she rescues Clemont’s wayward Chespin! Team Flare is also in Lumiose City, preparing for a secret operation while all eyes are on the League—and Lysandre has plans for Ash once the League is over. Meanwhile, Professor Sycamore, who has been researching Ash-Greninja, shows our heroes an old manuscript describing the mysterious Bond Phenomenon, which requires Trainer and Pokémon to have a particularly close connection. Afterward, Ash rallies his Pokémon for the battle ahead, while Alain trains hard with his Charizard. His mission to gather Mega Evolution energy is nearly complete...
Aired 04/08/2016EP 36 - Episode 36

Pokémon the Series: XYZ
The journey of Satoshi and his friends through the Kalos region continues! After Satoshi obtains his seventh gym badge, the group is moving toward the next town when Eureka discovers a mysterious Pokémon resting in her pochette. Soon given the name Puni-chan, it is one that even Satoshi and Serena's new Pokémon Zukan cannot identify. However, it quickly becomes apparent that Puni-chan is the target of a mysterious group clad in bright red suits known as Team Flare, aiming to capture the new Pokémon to further their agenda. But when Satoshi and the gang realize that the enigmatic organization has no intention of treating Puni-chan with any decency, they take a stand in opposition to Team Flare's plans, daring to fight back.
With Gojika's predictions looming above them, Satoshi aims for his final gym badge while Serena contests for her last Princess Key in order to be able to compete at the TriPokalon Master Class. But as Team Flare begins to move in search of the mysterious Z, the stories of Pokemon XY and Pokemon XY: Mega Evolution cross paths as Satoshi and his friends, along with Team Rocket, get caught up in a scheme that could put Kalos in great danger.
(Source: MAL Rewrite)