The Awakening Hyourinmaru!
Ichigo is still trapped in the ice prison Hyorinmaru imprisoned him in as Toshiro and Hyorinmaru confront each other. Meanwhile, Momo and Rangiku fight their zanpakutos in the woods and finally manage to overpower them with kido spells. As Hyorinmaru and Toshiro begin to fight, Toushiro tries to seal him but is shocked as Hyorinmaru effortlessly dissolves the seal into fragments of ice. As their fight continues, Hyorinmaru's tremendous power turns the whole of Soul Society's sky black.
Aired 29/09/2009EP 239 - The Awakening Hyourinmaru!

Bleach
Ichigo Kurosaki is a rather normal high school student apart from the fact he has the ability to see ghosts. This ability never impacted his life in a major way until the day he encounters the Shinigami Kuchiki Rukia, who saves him and his family's lives from a Hollow, a corrupt spirit that devours human souls.
Wounded during the fight against the Hollow, Rukia chooses the only option available to defeat the monster and passes her Shinigami powers to Ichigo. Now forced to act as a substitute until Rukia recovers, Ichigo hunts down the Hollows that plague his town.