Mystery! The Sword-Consuming Assassin
Refusing to give up Rurichiyo, Rukia uses her special ability to encase her new opponent Douko Jinnai in ice, but he easily breaks free.
Aired 25/06/2008EP 176 - Mystery! The Sword-Consuming Assassin

2004
Bleach
Ichigo Kurosaki is a rather normal high school student apart from the fact he has the ability to see ghosts. This ability never impacted his life in a major way until the day he encounters the Shinigami Kuchiki Rukia, who saves him and his family's lives from a Hollow, a corrupt spirit that devours human souls.
Wounded during the fight against the Hollow, Rukia chooses the only option available to defeat the monster and passes her Shinigami powers to Ichigo. Now forced to act as a substitute until Rukia recovers, Ichigo hunts down the Hollows that plague his town.