Episode 13
Lonely 5th grade teacher Namiko Gokumare hitches a ride to Six Gates and even helps the Knights in an adventure.
Aired 03/04/2000EP 13 - Episode 13

2000
Mon Colle Knights
Scientist Ichiroubei Hiiragi discovers the existence of Six Gates, an otherdimensional world full of monsters and powerful hidden treasures known as Mon Mon Items. Ichiroubei embarks with his daughter, Rokuna, and her classmate, Mondo. However, they're foiled at every turn by Count Collection and his assistants, who want the Mon Mon Items in order to conquer both worlds. Becoming the heroes known as Mon Colle Knights, Mondo and Rokuna join forces with the monsters, striking back against Count Collection while searching for the Mon Mon Items in the name of friendship between their worlds.
(Source: Crunchyroll)