VS Iron Man
Yinsen recalls when he was saved from being shot by terrorists by a woman named Sandra. Meanwhile, Tony is nearly finished with his arc reactor, but Yinsen apprehends the shipment of plutonium needed to complete it using the Dio armor. Iron Man and the two battle before Yinsen escapes with the plutonium, leaving Iron Man to fight the Zodiac warrior Sagittarius, but he soon loses him. Yinsen then contacts Stark, telling him that the people who rescued him were killed by Stark Industries weaponry. The two once again fight for the plutonium, with Yinsen insisting that Tony has not changed. He reveals several models of Iron Man Sigma, which he created by reverse engineering Dio, which he uses to attack the arc station. Yinsen defeats Tony, takes him out of his armor and chucks him into a river.
Aired 26/11/2010EP 9 - VS Iron Man

Iron Man
Tony Stark, CEO of a large weapons manufacturer, physicist, engineer, and brilliant inventor, is wounded by shrapnel from one of his own weapons. While held captive by terrorists, he develops the Iron Man Suit and escapes. From that day on, he vows not to waste his second chance at life and to change the world for the better. For that purpose, he comes to Japan.
In Lab 23 in Japan, great strides have been taken to develop, and build, a unique power station which does not run on fossil fuels, the Arc Station. Stark intends to join this project, and, for that, he is ready to announce his retirement as Iron Man. At the same time, he will also announce the Mass-produced Iron Men, to which he will pass on his duties. However, during the ceremonies, Stark is suddenly attacked by combat mecha belonging to an organization known as Zodiac.