Ah! I Shall Grant Your Wish!
Keiichi accidentally makes another call to the Goddess help line, and summons the goddess Peorth, who makes her debut in this episode. But since Keiichi already got what he wished for with Belldandy, he doesn't ask for anything else, but Peorth is intent on having Keiichi wish for something significant, and will stay there until he does.
Aired 18/05/2006EP 7 - Ah! I Shall Grant Your Wish!

2006
Oh! My Goddess: Flights of Fancy
The song may say "thank heaven for little girls", but who is college student Keiichi Morisato supposed to thank when three honest to goodness Goddesses move in and take over his life? After all, according to most mythologies, relationships between mortals and immortals usually leads to mortifying complications, so we're already talking about an extremely mixed blessing!
(Source: Crunchyroll)