Ah! My Darling Cupid!
Skuld develops her goddess magic skills, and gets inspired to summon her angel, but accidentally swallows the egg that holds her. The goddesses manage to extract the angel from Skuld's body and Noble Scarlet is born! The new little angel wants to help Skuld in any way she can, including setting her up with Sentaro.
Aired 07/07/2006EP 14 - Ah! My Darling Cupid!

2006
Oh! My Goddess: Flights of Fancy
The song may say "thank heaven for little girls", but who is college student Keiichi Morisato supposed to thank when three honest to goodness Goddesses move in and take over his life? After all, according to most mythologies, relationships between mortals and immortals usually leads to mortifying complications, so we're already talking about an extremely mixed blessing!
(Source: Crunchyroll)