Proof
Shura Kirigakure, a high level Exorcist and former apprentice of Father Shiro was acting as one of Rin's classmates tasked to investigate his connection with Satan. With orders to kill him if it were proven true, she is divided between fulfill her obligations and follow Shiro's request to look after Rin in his place if something would happen with him. Her doubts are cleared when she confronts Rin and finds that Shiro was actually raising him like a son instead of a weapon.
Aired 10/07/2011EP 13 - Proof
Blue Exorcist
This world consists of two dimensions joined as one, like a mirror. The first is the world in which the humans live, Assiah. The other is the world of demons, Gehenna. Ordinarily, travel between the two, and indeed any kind of contact between the two, is impossible. However the demons can pass over into this world by possessing anything that exist within it. Satan the god of demons, but there's one thing that he doesn't have, and that's a substance in the human world that is powerful enough to contain him!! For that purpose he created Rin, his son from a human woman, but will his son agree to his plans? Or will he become something else...? An exorcist?